2. Which of the following statements regarding silicon dioxide, SiO2, are correct?
I. The structure is described as a giant covalent structure with a tetrahedral arrangement
II. The structure is insoluble in water and has a high melting point
III. The structure has a pair of nonbonding electrons present on the silicon atoms
A
Explanation:
SiO2 has a giant covalent structure where each Si atom is singly bonded to four oxygen atoms (while maintaining a Si
ratio of 1:2).
As there are four electron domains around each silicon atom, the structure has a tetrahedral arrangement. SiO2 is held together by strong covalent bonds requiring a large amount of energy to overcome, resulting in a high melting point.
The strong bonds, together with the fact that there are no charged particles present, lead to insolubility in polar solvents such as water.