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HL - Models of Bonding & Structure

25 MCQ from 2025 Question Bank Models of Bonding & Structure (all topics)

DP IB HL Chemistry Quiz

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1. The structures of diamond and buckminsterfullerene are shown.

CH0702

Which of the following correctly describes the physical properties of the two materials?

  • Electrically conductive materials Hard materials
    A. Neither Both
    B. Neither Diamond only
    C. Buckminsterfullerene only Both
    D. Buckminsterfullerene only Diamond only

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2.

4.3-0338

The bond angles surrounding atoms 1, 2, and 3 are:

  • 2.
    Atom 1 Atom 2 Atom 3
    A. 90 120° 120
    B. 109.5 120 109.5
    C. 107 120 109.5
    D. 109.5 120° 107°

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3. Which statement correctly explains why the boiling point of 2-methylpentane is lower than that of hexane?

4.4-271

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4. Which molecule would be considered polar covalent?

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5. Ethene has the following structural formula:

14.2-380

Which orbitals of the carbon atoms are used to form the C−H and  bonds of ethene?

  • C−H bonds C=C bond
    A. sp^2 orbitals p orbitals
    B. p orbitals sp^2 and p orbitals
    C. sp^2 orbitals sp^ and p orbitals
    D. p orbitals sp^ orbitals

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6. Carbon tetrachloride has covalent bonding. Which of the following clearly describes this type of bonding?

 

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7. Which statement explains the high boiling point of NH3?

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8. Which statements regarding alloys are correct?

I. Alloys are a solid solution held together with metallic bonds
II. Because the lattice contains differing-size ions, the metallic bonds are weaker
III. Alloys can have different chemical properties than their component elements

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9. Which compounds have an ionic lattice in the solid state?

I. Ammonium sulfate
II. Hydrogen chloride
III. Sodium carbonate

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10. Sodium fluoride contains ionic bonding. Which statement correctly describes ionic bonding?

 

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11. A carbon atom is sp^ hybridized.
Which diagram best illustrates the valence electron configuration of this carbon atom?

  • A. 14.2-385a
  • B. 14.2-385b
  • C. 14.2-385c
  • D. 14.2-385d

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12. The tetrafluoroborate ion (BF4^−) is produced when boron trifluoride (BF3) reacts with a fluoride ion.

14.2-383

What is the hybridization of the boron atom in BF3and BF4^−?

  • BF3 BF4^−
    A. sp^3 sp^2
    B. sp^2 sp^3
    C. sp^2 sp^2
    D. sp^3 sp^3

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13. Hybridization is a system for explaining the changes in orbital energies and electron configurations when atoms form covalent bonds. Which of the following statements are true?

I. Paired electrons in an s orbital may occupy separate sp^ orbitals after hybridization
II. Hybridization leaves the number of atomic orbitals unchanged
III. A π bond forms from the sideways overlap of sp or sp^ orbitals

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14. Which of the following statements regarding silicon dioxide, SiO2, are correct?

I. The structure is described as a giant covalent structure with a tetrahedral arrangement
II. The structure is insoluble in water and has a high melting point
III. The structure has a pair of nonbonding electrons present on the silicon atoms

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15. Which of the following substances is the most soluble in water, with the correct reason given?
             Substance                                            Reason
A.            PF3                                 The bonds are very polar
B.           PF3                                The molecule has a permanent dipole
C.          NH3                               It can form hydrogen bonds with itself
D.          NH3                              It can form hydrogen bonds with water molecules

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16. Which shows the oxygen-to-oxygen bonds in order of increasing average bond enthalpy?

 

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17. Which of the below gives the intermolecular forces in water in the correct order from weakest to strongest?

 

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18. Which of the following is the correct formula for strontium sulfide?

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19. Based on their structures, which of the substances below is likely to be the most volatile?

 

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20. Which of the following statements correctly describes what happens when magnesium fluoride is formed?

 

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21. Metal M is in group 2 of the periodic table. Which is the correct formula?

 

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22. The electron configuration of carbon is 1s^2 2s^2 2p^2. Why is hybridization helpful for explaining the bonding of carbon in ethene (C2H4)?

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23. Based on single, double, and triple bonds, which set of molecules is arranged in increasing order of their bond strength?

 

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24. Which is NOTa characteristic property of metals resulting from metallic bonding?

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25. What is the correct number of total valence electrons and electron domains on the central atom for the methanal molecule, CH2O?

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