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HL - Models of Bonding & Structure

25 MCQ from 2025 Question Bank Models of Bonding & Structure (all topics)

DP IB HL Chemistry Quiz

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1. Which of the following substances is the most soluble in water, with the correct reason given?
             Substance                                            Reason
A.            PF3​                                 The bonds are very polar
B.           PF3​                                The molecule has a permanent dipole
C.          NH3​                               It can form hydrogen bonds with itself
D.          NH3​                              It can form hydrogen bonds with water molecules

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2. Which of the following are characteristics of transition elements?

  • I. High melting points
  • II. Soft
  • III. Electrically conductive

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3. The tetrafluoroborate ion (BF4^−) is produced when boron trifluoride (BF3) reacts with a fluoride ion.

14.2-383

What is the hybridization of the boron atom in BF3and BF4^−?

  • BF3 BF4^−
    A. sp^3 sp^2
    B. sp^2 sp^3
    C. sp^2 sp^2
    D. sp^3 sp^3

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4. The molecule O2 contains one σ and one  bond. How do p orbitals in the  atoms overlap to produce the  bond?

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5.

4.3-0338

The bond angles surrounding atoms 1, 2, and 3 are:

  • 5.
    Atom 1 Atom 2 Atom 3
    A. 90 120° 120
    B. 109.5 120 109.5
    C. 107 120 109.5
    D. 109.5 120° 107°

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6. Which of the following statements correctly describes what happens when magnesium fluoride is formed?

 

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7. Based on single, double, and triple bonds, which set of molecules is arranged in increasing order of their bond strength?

 

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8. Which is NOTa characteristic property of metals resulting from metallic bonding?

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9. Ethene has the following structural formula:

14.2-380

Which orbitals of the carbon atoms are used to form the C−H and  bonds of ethene?

  • C−H bonds C=C bond
    A. sp^2 orbitals p orbitals
    B. p orbitals sp^2 and p orbitals
    C. sp^2 orbitals sp^ and p orbitals
    D. p orbitals sp^ orbitals

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10. Which of the below gives the intermolecular forces in water in the correct order from weakest to strongest?

 

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11. Which characteristic best corresponds to, or indicates, the strength of metallic bonding?

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12. Covalent bonds result from the overlap of atomic orbitals.
Which of the following atomic orbitals would overlap to produce a σ bond in the orientation shown?

  • A. CH0505A
    B. CH0505B
    C. CH0505C
    D. CH0505D

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13. What is the formula of the compound formed between lithium and nitrogen?

 

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14. Which correctly states the relative size of the bond angles for HO, NH, and CH?

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15. Which bond is more polar?

 

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16. Which of the following polyatomic ions formulas is incorrect?

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17. Which statement explains the high boiling point of NH3?

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18. In which instance is ionic bonding most likely to occur?

 

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19. Which of the following cannot conduct electricity in a molten state?

I. PCl3​
II. NaCl
III. SO2

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20. Metallic bonding is best characterized by the following statement:

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21. Which properties are typical of ionic compounds?
                Volatility             Solubility in polar solvents
A.             High                               Good
B.             Low                                 Good
C.             High                                Poor
D.             Low                                 Poor

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22. Hybridization is a system for explaining the changes in orbital energies and electron configurations when atoms form covalent bonds. Which of the following statements are true?

I. Paired electrons in an s orbital may occupy separate sp^ orbitals after hybridization
II. Hybridization leaves the number of atomic orbitals unchanged
III. A π bond forms from the sideways overlap of sp or sp^ orbitals

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23. Which of the following explains why transition metals have high melting points?

 

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24. Which compounds have an ionic lattice in the solid state?

I. Ammonium sulfate
II. Hydrogen chloride
III. Sodium carbonate

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25. Which statements are correct about lattice enthalpies?

I. Salts with smaller lattice enthalpies have higher melting points
II. The lattice enthalpy depends on the charge of the constituent ions
III. The lattice enthalpy depends on the size of the constituent ions

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