Explanation:
Recall of transition metal properties.

Explanation:
First ionization energy decreases down a group due to increased shielding (number of shells). Beryllium must therefore have a higher first IE than magnesium. And similarly, oxygen higher than sulfur.
First ionization energy increases across a period due to increased nuclear charge for the same number of shells. Hence, oxygen has higher first IE than beryllium.

Explanation:
Statement III is not correct as physical properties, including melting point and metallic character, change dramatically across a period due to changes in nuclear charge for the same number of shells.
Elements in the periodic table are arranged in increased atomic number.
Anions are atoms that have gained electrons. This will increase the electron-electron repulsion in the outermost shell, and will cause the electrons to move further apart.Therefore, the radius of the outershell will increase.

Explanation:
Saturated compounds contain only single bonds.
Butyne is an alkyne, and so, has a triple bond.

Explanation:
C3H6 belongs to the alkene class with the general formula CnH2n, and has a three carbon chain.

Explanation:
This question tests the ability of the student to convert a 3D model to wedge-dash notation.
The difficulty is low as the shape of the model is close to that of the 2D representation – no rotation around the single bonds is needed to determine the relative orientations of the substituent groups.

Carbon-1 is attached to an H-atom coming out of the page (wedge bond), an NH2 group going into the page (dashed bond), and a CH3 group in the plane of the page.
Carbon-2 is attached to a $\mathrm{Cl}$ atom coming out of the page (wedge bond), an H atom going into the page (dashed bond), and a CH3 group in the plane of the page.

Explanation:

The electron configuration of the atom is 1s^2 2s^2 2p^4. There are 8 electrons in total and the electron configuration corresponds to a neutral atom, so the atomic number must be 8 also. The element is oxygen and it lies in group 16 $\text{OR}$ since the atom has 6 valence electrons, its element should be located in group 16.

There are two subshells so the period number is 2. This question is moderately difficult as the student must deduce that the number of electrons is equal to the atomic number or determine which of the orbitals are part of different shells, without the assistance of orbital labels.

Explanation:
Structural isomers have the same molecular formula but different structural formulae.
Methoxyethane and propanol both have the molecular formula C3H8O.

Explanation:
Atomic radius and metallic character decrease across a period. Ionization energy decreases down a group due to increased shielding.

Explanation:

The group of an element is determined by its atomic number, which is found in the lower left corner of the element symbol. Although this conflicts with the representation in the data booklet, students should be able to differentiate between the mass and atomic number based on their relative size. The elements represented by options A, B, C and D are calcium (an alkaline earth metal), iron (a transition metal), gallium (a poor / p block metal) and rubidium (an alkali metal), respectively. This question is moderately difficult as the student must identify the correct value from the given symbol and relate it to the position of an element in the periodic table.

Explanation:
NH3 has a non-bonding pair of electrons it can donate to a central metal ion. BH3 and CH4 do not have non-bonding electrons.

Explanation:
Ligands are Lewis bases with a lone pair of electrons that they can donate to a central metal ion.

Explanation:
Statement II is incorrect as acids produce solutions with $\mathrm{pH}$ lower than 7

Explanation:
The longest carbon chain has 5 carbons and will include the C=C.
The alkene is given priority and is on carbon-1.
The methyl group is bonded to carbon-2.

Explanation:
Increasing atomic radius results in a weaker electrostatic force of attraction between the nucleus and electrons in the covalent bond. An increased number of shells down the group increases the shielding between the nucleus and electrons in the covalent bond.

Explanation:
The student must recognise that there are three proton environments in a 3:2:3 ratio;
B has only $2$ environments ($3:2$ ratio), while C has 4 (3:2:2:1). D has $3$ environments but they are in a 6:1:1 ratio.
The question is hard as two pieces of information must be extracted from the spectrum and interpreted in the context of the structural formulas given.

Explanation:
The 6 protons in the nucleus of carbon will exert a stronger attractive force on the second energy level electrons than the 5 protons of boron.
Increasing electron affinity from left to right across a period.

Explanation:
The student must recall the definition of a racemic mixture and understand how the wedge-dash notation varies between enantiomers.
A racemic mixture includes both optical isomers in equal amounts. Option A is the same molecule (possibly a conformational isomer), option C is a diastereomer, and option D is a structural/positional isomer.

Metalloids lie on the boundary between metals and non-metals in the p block of the periodic table. They are shiny like metals but brittle like non-metals, and can switch between being electrical insulators and electrical conductors. Although this switchable conductivity could be considered as a change from metal-like to non-metal-like behaviour, it does not affect all properties of the element: the element does not switch from being a metal to a non-metal.

Metalloids do not contain incomplete d subshells (this is a property of transition metals) and lie alongside the poor metals in the p block of the periodic table. This question is categorised as moderately difficult as the concept of metalloids is not covered extensively in the syllabus, though the distinction between metals, non-metals and metalloids is highlighted.

Explanation:
Group 17 melting points increase down the group due to increased strength in intermolecular forces. The molecular structures of each element are held together by London (dispersion) forces. These increase with the number of electrons in the molecule. Therefore statement I is not true, but III is.
Group 1 melting points decrease down a group due to decreasing metallic bond strength (with increase of atomic radius), therefore statement II is also true.

Explanation:
NH2 is the amine functional group, RCOOR′ is the ester functional group.

Explanation:
The masses of options A, B, C and D are 29, 45, 31 and 28, respectively.
The mass of the fragment ion is 148 - 117 = 31, making option C correct.
This question is of moderate difficulty as two simple calculations are required

Explanation:
Choices III and IV are ethene and ethyne with a double bond and a triple bond, respectively. They belong to the classes of alkenes and alkynes, which can be deduced by the general formulae, CnH2n and CnH2n−2 .
Choice I is the alkane methane, and choice II is a halogenoalkane (chloromethane).

Explanation:
Each $\mathrm{Cl}$ ligand has a 1-charge.
2+(4x−1)=2−.
As outlined in the Chemistry Guide, [CuCl4]^2− has a tetrahedral shape.