Explanation:
The masses of options A, B, C and D are 29, 45, 31 and 28, respectively.
The mass of the fragment ion is 148 - 117 = 31, making option C correct.
This question is of moderate difficulty as two simple calculations are required

Explanation:
A tertiary amine is when three carbon groups are attached to the amine.

Explanation:
There are 4 proton environments as the CH(CH3)2 protons are equivalent. Integration gives the relative number of protons in each environment. There are 3 on C1, 2 on C2, 1 of C3 and 6 on C4 and 5.

Explanation:

The group of an element is determined by its atomic number, which is found in the lower left corner of the element symbol. Although this conflicts with the representation in the data booklet, students should be able to differentiate between the mass and atomic number based on their relative size. The elements represented by options A, B, C and D are calcium (an alkaline earth metal), iron (a transition metal), gallium (a poor / p block metal) and rubidium (an alkali metal), respectively. This question is moderately difficult as the student must identify the correct value from the given symbol and relate it to the position of an element in the periodic table.

Explanation:

Lithium is in group 1 and so forms Li^+ ions. The formula of the nitride ion is N^3−as nitrogen is in group 15. For the positive and negative charges to cancel out, three Li+ ions are needed for each N3− ion.

Explanation:
Statement III is not correct as physical properties, including melting point and metallic character, change dramatically across a period due to changes in nuclear charge for the same number of shells.
Elements in the periodic table are arranged in increased atomic number.
Anions are atoms that have gained electrons. This will increase the electron-electron repulsion in the outermost shell, and will cause the electrons to move further apart.Therefore, the radius of the outershell will increase.

Explanation:
The longest carbon chain has 5 carbons and will include the C=C.
The alkene is given priority and is on carbon-1.
The methyl group is bonded to carbon-2.

Explanation:
Choices III and IV are ethene and ethyne with a double bond and a triple bond, respectively. They belong to the classes of alkenes and alkynes, which can be deduced by the general formulae, CnH2n and CnH2n−2 .
Choice I is the alkane methane, and choice II is a halogenoalkane (chloromethane).

Explanation:
Simple recognition of the units used in an IR spectrum. Since the information is given in the syllabus and covered frequently, this question is categorised as easy

Explanation:
Statement II is incorrect as acids produce solutions with $\mathrm{pH}$ lower than 7

Explanation:
In HBrO, the oxidation states of both H and Br are +1.

Explanation:
First ionization energy decreases down a group due to increased shielding (number of shells). Beryllium must therefore have a higher first IE than magnesium. And similarly, oxygen higher than sulfur.
First ionization energy increases across a period due to increased nuclear charge for the same number of shells. Hence, oxygen has higher first IE than beryllium.

Explanation:
Recall of transition metal properties.

Explanation:
Group 17 melting points increase down the group due to increased strength in intermolecular forces. The molecular structures of each element are held together by London (dispersion) forces. These increase with the number of electrons in the molecule. Therefore statement I is not true, but III is.
Group 1 melting points decrease down a group due to decreasing metallic bond strength (with increase of atomic radius), therefore statement II is also true.

Explanation:
This question tests the ability of the student to convert a 3D model to wedge-dash notation.
The difficulty is low as the shape of the model is close to that of the 2D representation – no rotation around the single bonds is needed to determine the relative orientations of the substituent groups.

Carbon-1 is attached to an H-atom coming out of the page (wedge bond), an NH2 group going into the page (dashed bond), and a CH3 group in the plane of the page.
Carbon-2 is attached to a $\mathrm{Cl}$ atom coming out of the page (wedge bond), an H atom going into the page (dashed bond), and a CH3 group in the plane of the page.

Explanation:
NH3 has a non-bonding pair of electrons it can donate to a central metal ion. BH3 and CH4 do not have non-bonding electrons.

Explanation:
Each $\mathrm{Cl}$ ligand has a 1-charge.
2+(4x−1)=2−.
As outlined in the Chemistry Guide, [CuCl4]^2− has a tetrahedral shape.

Explanation:
Ethers contain C−O single bonds $\text{not}$ the $\mathrm{C}=\mathrm{O}$ carbonyl group.

Explanation:
Increasing atomic radius results in a weaker electrostatic force of attraction between the nucleus and electrons in the covalent bond. An increased number of shells down the group increases the shielding between the nucleus and electrons in the covalent bond.

Explanation:

The atomic number of Cr is higher than that of V by 1, and its relative atomic mass is also higher by approximately 1. The atomic number is unique for each element and dictates the position of the element in the periodic table; thus, Cr always has an atomic number of 24 and vanadium an atomic number of 23. However, isotopes of an element may have different atomic masses, so an atom of Cr may have a lower atomic mass than an atom of V. This question is categorised as easy since the difference between atomic number and atomic mass and the variation in mass between isotopes of an element are covered extensively in the syllabus.

Explanation:
The 6 protons in the nucleus of carbon will exert a stronger attractive force on the second energy level electrons than the 5 protons of boron.
Increasing electron affinity from left to right across a period.

Explanation:
The air is naturally composed of 0.04% carbon dioxide, which dissolves in water to form the weak carbonic acid

Explanation:
Acid rain is formed from sulfur and nitrogen oxides dissolving in the clouds.

Explanation:
C3H6 belongs to the alkene class with the general formula CnH2n, and has a three carbon chain.