Explanation:
The student must recognise that there are three proton environments in a 3:2:3 ratio;
B has only $2$ environments ($3:2$ ratio), while C has 4 (3:2:2:1). D has $3$ environments but they are in a 6:1:1 ratio.
The question is hard as two pieces of information must be extracted from the spectrum and interpreted in the context of the structural formulas given.

Explanation:
A tertiary amine is when three carbon groups are attached to the amine.

Explanation:
Group 17 melting points increase down the group due to increased strength in intermolecular forces. The molecular structures of each element are held together by London (dispersion) forces. These increase with the number of electrons in the molecule. Therefore statement I is not true, but III is.
Group 1 melting points decrease down a group due to decreasing metallic bond strength (with increase of atomic radius), therefore statement II is also true.

Explanation:

The names of the labelled groups are covered explicitly in the syllabus.

Explanation:
Acid rain is formed from sulfur and nitrogen oxides dissolving in the clouds.

Explanation:

Elements in the same group (column) of the periodic table have the same number of outer shell (valence) electrons, represented by the group number; the number of electron shells increases down the group. Elements in the same row (period) have the same number of electron shells (or principal quantum number), equal to the period number; the number of valence electrons increases across the period. This question is moderately difficult as the student must recall multiple pieces of information and correctly interpret a schematic illustration of the periodic table.

Explanation:
The attraction for a shared pair of electrons in a covalent bond depends on electronegativity. Carbon has the lowest electronegativity value of the given elements across period 2, it has the lowest effective nuclear charge (least number of protons attracting valence electrons in energy level 2). Increasing electronegativity across a period from left to right.

Explanation:
Structural isomers have the same molecular formula but different structural formulae.
Methoxyethane and propanol both have the molecular formula C3H8O.

Explanation:
Across the same period, metals have lower ionization energies than non-metals due to lower nuclear charges with the same number of shells (shielding effect).

Explanation:
Saturated compounds contain only single bonds.
Butyne is an alkyne, and so, has a triple bond.

Explanation:
The electron configuration of Zn2+ is [Ar] 3d^10. There are no vacancies in the $d$ subshell so a transition between the split energy levels of the octahedral complex is not possible.
This question is categorized as easy as the colourless nature of d10 ions is covered explicitly in the syllabus.

Explanation:

Lithium is in group 1 and so forms Li^+ ions. The formula of the nitride ion is N^3−as nitrogen is in group 15. For the positive and negative charges to cancel out, three Li+ ions are needed for each N3− ion.

Explanation:
C3H6 belongs to the alkene class with the general formula CnH2n, and has a three carbon chain.

Explanation:
Ligands are Lewis bases with a lone pair of electrons that they can donate to a central metal ion.

Explanation:
The air is naturally composed of 0.04% carbon dioxide, which dissolves in water to form the weak carbonic acid

Explanation:

The atomic number of Cr is higher than that of V by 1, and its relative atomic mass is also higher by approximately 1. The atomic number is unique for each element and dictates the position of the element in the periodic table; thus, Cr always has an atomic number of 24 and vanadium an atomic number of 23. However, isotopes of an element may have different atomic masses, so an atom of Cr may have a lower atomic mass than an atom of V. This question is categorised as easy since the difference between atomic number and atomic mass and the variation in mass between isotopes of an element are covered extensively in the syllabus.

Explanation:
NH3 has a non-bonding pair of electrons it can donate to a central metal ion. BH3 and CH4 do not have non-bonding electrons.

Explanation:

The electron configuration of the atom is 1s^2 2s^2 2p^4. There are 8 electrons in total and the electron configuration corresponds to a neutral atom, so the atomic number must be 8 also. The element is oxygen and it lies in group 16 $\text{OR}$ since the atom has 6 valence electrons, its element should be located in group 16.

There are two subshells so the period number is 2. This question is moderately difficult as the student must deduce that the number of electrons is equal to the atomic number or determine which of the orbitals are part of different shells, without the assistance of orbital labels.

Explanation:

The group of an element is determined by its atomic number, which is found in the lower left corner of the element symbol. Although this conflicts with the representation in the data booklet, students should be able to differentiate between the mass and atomic number based on their relative size. The elements represented by options A, B, C and D are calcium (an alkaline earth metal), iron (a transition metal), gallium (a poor / p block metal) and rubidium (an alkali metal), respectively. This question is moderately difficult as the student must identify the correct value from the given symbol and relate it to the position of an element in the periodic table.

Explanation:
Ethers contain C−O single bonds $\text{not}$ the $\mathrm{C}=\mathrm{O}$ carbonyl group.

Explanation:
The student must recognise that the described technique is IR spectroscopy, and correctly interpret the diagram to identify a wavelength in the IR range.
The question is of moderate difficulty as it requires both the definition and the diagram to be understood correctly.

Explanation:
First ionization energy decreases down a group due to increased shielding (number of shells). Beryllium must therefore have a higher first IE than magnesium. And similarly, oxygen higher than sulfur.
First ionization energy increases across a period due to increased nuclear charge for the same number of shells. Hence, oxygen has higher first IE than beryllium.

Metalloids lie on the boundary between metals and non-metals in the p block of the periodic table. They are shiny like metals but brittle like non-metals, and can switch between being electrical insulators and electrical conductors. Although this switchable conductivity could be considered as a change from metal-like to non-metal-like behaviour, it does not affect all properties of the element: the element does not switch from being a metal to a non-metal.

Metalloids do not contain incomplete d subshells (this is a property of transition metals) and lie alongside the poor metals in the p block of the periodic table. This question is categorised as moderately difficult as the concept of metalloids is not covered extensively in the syllabus, though the distinction between metals, non-metals and metalloids is highlighted.

Explanation:
Simple recognition of the units used in an IR spectrum. Since the information is given in the syllabus and covered frequently, this question is categorised as easy

Explanation:
Recall of transition metal properties.