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HL - Models of Bonding & Structure

25 MCQ from 2025 Question Bank Models of Bonding & Structure (all topics)

DP IB HL Chemistry Quiz

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1. What is the correct number of total valence electrons and electron domains on the central atom for the methanal molecule, CH2O?

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2. The Lewis structure of NCl3 is given below. Which type(s) of electrons does it show?

4.2-0287

I. Non-Bonding Electrons
II. Bonding Electrons
III. Innermost electrons

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3. Which of the following is the correct order for % ionic character from highest to lowest for the following compounds?

 

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4. The structural formulas of two compounds in a homologous series are shown.

CH0788

Why does the boiling point of compound Y differ from that of compound X?

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5. Which of the following is the correct formula for strontium sulfide?

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6. Which of the following substances is the most soluble in water, with the correct reason given?
             Substance                                            Reason
A.            PF3                                 The bonds are very polar
B.           PF3                                The molecule has a permanent dipole
C.          NH3                               It can form hydrogen bonds with itself
D.          NH3                              It can form hydrogen bonds with water molecules

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7. A carbon atom is sp^ hybridized.
Which diagram best illustrates the valence electron configuration of this carbon atom?

  • A. 14.2-385a
  • B. 14.2-385b
  • C. 14.2-385c
  • D. 14.2-385d

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8. Which of the following statements correctly describes what happens when magnesium fluoride is formed?

 

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9. The tetrafluoroborate ion (BF4^−) is produced when boron trifluoride (BF3) reacts with a fluoride ion.

14.2-383

What is the hybridization of the boron atom in BF3and BF4^−?

  • BF3 BF4^−
    A. sp^3 sp^2
    B. sp^2 sp^3
    C. sp^2 sp^2
    D. sp^3 sp^3

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10. The structures of diamond and buckminsterfullerene are shown.

CH0702

Which of the following correctly describes the physical properties of the two materials?

  • Electrically conductive materials Hard materials
    A. Neither Both
    B. Neither Diamond only
    C. Buckminsterfullerene only Both
    D. Buckminsterfullerene only Diamond only

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11. Which of the following are characteristics of transition elements?

  • I. High melting points
  • II. Soft
  • III. Electrically conductive

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12. Which statements are correct about lattice enthalpies?

I. Salts with smaller lattice enthalpies have higher melting points
II. The lattice enthalpy depends on the charge of the constituent ions
III. The lattice enthalpy depends on the size of the constituent ions

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13. CH3COOH has which of the following intermolecular forces?

I. London
II. Dipole-Dipole
III. Hydrogen bonds

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14. What is the formula of the compound formed between lithium and nitrogen?

 

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15. Which properties are typical of ionic compounds?
                Volatility             Solubility in polar solvents
A.             High                               Good
B.             Low                                 Good
C.             High                                Poor
D.             Low                                 Poor

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16. The molecule O2 contains one σ and one  bond. How do p orbitals in the  atoms overlap to produce the  bond?

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17. Which shows the oxygen-to-oxygen bonds in order of increasing average bond enthalpy?

 

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18. Which is a correct description of the bonding present in the following allotropes of carbon?

  • Graphene Diamond Graphite
    A. 3-dimensional material with bond angles of 109.5 2-dimensional material with bond angles of 120 Hexagonal layers with bond angles of 120
    B. Hexagonal layers with bond angles of 120° 3-dimensional material with bond angles of 109.5 2-dimensional material with bond angles of 120
    C. 2-dimensional material with bond angles of 120 3-dimensional material with bond angles of 109.5 Hexagonal layers with bond angles of 120
    D. 2-dimensional material with bond angles of 120 Hexagonal layers with bond angles of 120 3-dimensional material with bond angles of 109.5

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19. Covalent bonds result from the overlap of atomic orbitals.
Which of the following atomic orbitals would overlap to produce a σ bond in the orientation shown?

  • A. CH0505A
    B. CH0505B
    C. CH0505C
    D. CH0505D

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20. Metal M is in group 2 of the periodic table. Which is the correct formula?

 

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21. Ethyne has the molecular formula C2H2.
Which of the following best illustrates the arrangement of hybridized valence orbitals in each carbon atom?

  • A.14.2-379a
  • B.14.2-379b
  • C.14.2-379c
  • D.14.2-379d

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22. Which characteristic best corresponds to, or indicates, the strength of metallic bonding?

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23. Sodium fluoride contains ionic bonding. Which statement correctly describes ionic bonding?

 

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24. Which of the following characteristics of transition metals results in high electrical conductivity?

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25. Hybridization is a system for explaining the changes in orbital energies and electron configurations when atoms form covalent bonds. Which of the following statements are true?

I. Paired electrons in an s orbital may occupy separate sp^ orbitals after hybridization
II. Hybridization leaves the number of atomic orbitals unchanged
III. A π bond forms from the sideways overlap of sp or sp^ orbitals

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